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来自 : www.lookchem.com/chemical-dict 发布时间:2021-03-26
产品名称:阿拉伯胶英文品名:arable gumCas号:9000-01-5 \"I别名:阿拉伯树胶:金合欢胶;亚克西胶;塞内加尔胶;桃胶分子结构:230)this.width=230;\" onerror=\"javascript:this.src=\'/images/err.gif\'\" src=\"http://www.lookchem.cn/ProImage/2009-11/a9e7ca9e-117e-44f9-9399-2e0822daf65f.bmp\" border=\"0\" alt=\" 9000-01-5 (阿拉伯胶) 的分子结构 \" align=\"absmiddle\"/>分子式:N/A分子量:220000EINECS:232-519-5危险品标志:IrritantXi化学属性:阿拉伯胶(9000-01-5)的相关性质如下:
1、相对密度1335~1.49。
2、黄色至浅黄褐色半透明块状物或白色至淡黄色粉末,无臭,无味。
3、易溶于水成黏稠液,不溶于乙醇等大多数有机溶剂。
4、在水中溶解度可达50%,水溶液呈弱酸性,但不形成凝胶。
5、可与羧甲基纤维素、蛋白质、糖、淀粉和大多数水溶性胶相配伍,但明胶和三价金属离子盐会使阿拉伯胶液发生沉淀。
6、兔子经口LD505g/kg,ADI不需特殊规定(FAO/WHO,1994)。用途:阿拉伯胶(9000-01-5)的用途:
按我国GB2760-86规定,作为增稠剂可用于饮料、巧克力、冰淇淋和果酱,最大用量为0.5-5.0g/kg。按FAO/WHO(1984)规定,用途及限量为:稀奶油5g/kg(单用或与其他增稠剂和改性剂合用量,仅用于巴氏杀菌掼奶油或掼打用的超高温杀菌稀奶油和消毒稀奶油);冷饮10g/kg(以最终产品计,单用或与其他乳化剂、稳定剂和增稠剂合用量);青刀豆和黄刀豆、甜玉米、蘑菇、芦笋、青豌豆等罐头10g/kg(单用或与其他增稠剂合用量,产品中含奶油或其他油脂);加工干酪制造8g/kg(单用或与其他增稠剂合用量);酸黄瓜500g/kg(单用或与其他助溶剂和分散剂合用量);胡萝卜罐头10g/kg(单用或与其他增稠剂合用量)。亦用作胶质硬糖或胶质凝胶糖的稳定剂。糖果的抗结晶剂及抛光剂。使用时需过滤。描述:阿拉伯胶(9000-01-5)的制备方法:
从阿拉伯胶树(Acacia senegal)或亲缘种金合欢属树A.seyal的茎和枝割流收集胶状渗出物,除去杂质后经干燥并粉碎而成。前者成品比后者为脆。

质量指标:
(FAO/WHO—1995):干燥失重,颗粒状(105℃,5h)≤15%,比旋光度aD20(干基计)为-26°~-34°;喷雾干燥法者(105℃,4h)≤10%;总灰分≤4%;氮(凯氏定氮法)0.27%~0.39%;酸不溶灰分≤0.5%;酸不溶物≤1%;淀粉或糊精、单宁结合胶阴性;砷(以As计)≤0.0003%;铅≤0.001%;重金属(以Pb计)≤0.004%;沙门氏菌阴性;大肠菌群阴性。

限量:
1.GB 2760-96:各类食品,GMP。
2.FAO/WHO(1984,g/kg):青刀豆和黄刀豆、甜玉米、蘑菇、芦笋、青豌豆等罐头10(产品中含奶油或其他油脂者);加工干酪制造8;酸黄瓜500;胡萝卜罐头10;稀奶油5(仅用于巴氏杀菌掼奶油或掼打用的超高温杀菌稀奶油和消毒稀奶油);冷饮10。
3.FDA,§184.1330(2000):饮料和固体饮料2.0%;胶姆糖5.6 %;糖食与糖霜12.4%;乳制品1.3%;油脂1.5%;明胶、布丁和馅料2.5%;硬糖、止咳糖46.5%;果仁制品8.3%;冷冻甜食6.0%;小吃食品4.0%;软糖85.0%;其他食品1.0%。
4.FEMA(mg/kg):软饮料330;冷饮430;糖果410;焙烤食品460;凝胶食品和布丁840;胶姆糖740~2800;蛋白酥皮750~7000;糖浆210~240。

鉴别试验:
1.1g试样溶于2ml水中,应形成易流动并对石蕊试纸呈酸性的溶液;不溶于乙醇(OT-42)。
2.经硅藻土过滤的10%试样液得自A.senegal的,呈轻度左旋;得自A.seyal者,呈右旋。
3.按下述方法鉴别阿拉伯糖、半乳糖、鼠李糖和葡萄糖醛酸:将试样100mg与10%硫酸20ml的混合液煮沸3h。放冷后,用磁性搅拌器混合,加过量的碳酸钡至溶液的pH值为7,过滤。滤液在真空旋转蒸发器中于30~50℃下蒸发至取得结晶或浆状残渣。溶于10mL 40%甲醇中,即为水解液。在两块色谱板的起点线上,标滴1~10,水解液(方法参见GT-10),以及含有1~10μg阿拉伯糖、半乳糖、鼠李糖和葡糖醛酸(预期存在于水解液中者)的溶液。每块色谱板分别用两种展开溶剂:A为:甲酸:丁酮:叔丁醇:水=15:30:40:15(以体积计);B为异丙醇:吡啶:醋酸g水=40:40:5:20(以体积计)。展开后,用由1.23g茴香胺和1.66g苯二甲酸溶于100ml乙醇所组成的溶液喷射,并在100℃下加热色谱板10min。如有己糖则呈现黄绿色,有戊糖呈现红色,有糖醛酸呈现棕色。将试样液色斑与含阿拉伯糖、半乳糖、鼠李糖和葡萄糖醛酸标准溶液的色斑进行对比。

质量指标分析:
1.干燥失重:按GT-19方法测定。条件为在105℃干燥5h。对未磨碎的试样,应研磨成能通过40目筛的粉末,并在称重前混匀。
2.淀粉或糊精:配制2%试样液,煮沸,冷却后加碘试液(TS-124)数滴。不得有浅蓝色或浅红色出现。
3.含丹宁树胶:取2%试样液10ml,约加0.1ml氯化铁试液(TS-101)。不得产生黑色或黑色沉淀。阿拉伯胶 的供应商 CAS No.9000-01-5 Arabic gum

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发布于 : 2021-03-26 阅读(0)
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